On our Jeep AIR systems, the diverter valve is designed to send air to the manifolds by default. On decleration when vacuum levls are their highest, the valve diverts pump air to the atmosphere.
With an air tube to the cat, pump air is diverted to the tube when a coolant switch is activated and if I remember correctly after all these years, the AIR pump supplies both simultaneously once the coolant temp rises to a certain point. Your system should have two diverter valves or a single unit with both combined.
Yes, there is a range of jet sizes for the MC 2xxx series out there. I used to dig through stockers at the salvage yard and drill the smaller ones out to get the sizes I needed...because poor and cheap